Time-Resolved X-ray Absorption Spectroscopy by Dispersive XAFS Technique

Time-resolved x-ray absorption spectroscopy: Watching atoms dance

The introduction of pump-probe techniques to the field of x-ray absorption spectroscopy (XAS) has allowed the monitoring of both structural and electronic dynamics of disordered systems in the condensed phase with unprecedented accuracy, both in time and in space. We present results on the electronically excited high-spin state structure of an Fe(II) molecular species, [Fe(bpy)3] , in aqueous s...

X-Ray Absorption Fine Structure (XAFS) Spectroscopy – A Review

X-ray absorption spectroscopy (XAS) refers to the details of how X-rays are absorbed by an atom at energies near and above the core-level binding energies of that particular atom. The absorption of X-rays on the high energy side of absorption edges does not vary monotonically in condensed matter but has a complicated behavior which extends past the edge up to about ~1 keV. This non-monotonic va...

Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy

We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x...

Stopped-flow X-ray Absorption Spectroscopy in Dispersive Mode

X-ray Magnetic Absorption and Scattering (XAFS)

1.Introduction In 3rd generation synchrotron radiation (SR), one of the most promising items may be control and characterization of polarization state. In particular, they are a crucial factor to study magnetic properties using the various techniques inscattering, absorption, diffraction and emission experiments. Indeed, low emittance SR such as Spring-8 can efficiently realize this performance...